Which of the following elements is extracted by electrolysis reduction?

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RRB Technician Grade III Official Paper (Held On: 28 Dec, 2024 Shift 2)
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  1. Na
  2. Ag
  3. Pb
  4. Zn

Answer (Detailed Solution Below)

Option 1 : Na
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Detailed Solution

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The correct answer is Na.

Key Points

  • Sodium (Na) is extracted by electrolysis of molten sodium chloride (NaCl).
  • The process is known as the Downs process, where molten sodium chloride is electrolyzed.
  • During electrolysis, sodium ions are reduced at the cathode to form sodium metal.
  • Sodium is highly reactive and cannot be extracted by simple reduction methods, necessitating the use of electrolysis.
  • Electrolysis is crucial for extracting highly reactive metals like sodium from their compounds.

Additional Information

  • Electrolysis Process
    • Electrolysis involves passing an electric current through a molten or aqueous solution to cause a chemical change.
    • It is widely used for extracting metals from their ores and purifying them.
    • The process is performed in an electrolytic cell, which consists of two electrodes: an anode and a cathode.
    • During electrolysis, cations move towards the cathode to gain electrons (reduction), and anions move towards the anode to lose electrons (oxidation).
  • Downs Process
    • This process is specifically used for the extraction of sodium metal from molten sodium chloride.
    • It involves the use of a carbon anode and an iron cathode in a molten sodium chloride bath.
    • Sodium is collected at the cathode, while chlorine gas is produced at the anode.
    • Calcium chloride is often added to lower the melting point of sodium chloride in this process.
  • Reactivity Series
    • The reactivity series is a list of elements ordered by their reactivity.
    • Sodium is placed high in the reactivity series, indicating its high reactivity.
    • Highly reactive metals like sodium cannot be extracted by simple chemical reduction methods.
    • Electrolysis is necessary for extracting these metals from their compounds.
  • Applications of Sodium
    • Sodium is used in various industrial processes, including the manufacture of sodium compounds and in the reduction of metals.
    • It is also used in street lighting and as a heat exchanger in some nuclear reactors.
    • Sodium compounds, such as sodium chloride and sodium hydroxide, have numerous applications in industries and households.
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