Thermodynamics MCQ Quiz - Objective Question with Answer for Thermodynamics - Download Free PDF

Last updated on Jun 24, 2025

Latest Thermodynamics MCQ Objective Questions

Thermodynamics Question 1:

When steam is converted into water, internal energy of the system

  1. Becomes zero
  2. Remains constant
  3. Increases
  4. Decreases

Answer (Detailed Solution Below)

Option 4 : Decreases

Thermodynamics Question 1 Detailed Solution

The correct answer is Decreases.

Key Points

  • When steam condenses into water, it undergoes a phase change from gas to liquid, releasing latent heat in the process.
  • This release of latent heat leads to a decrease in the internal energy of the system.
  • The internal energy of a system is directly related to the kinetic and potential energy of its molecules; in the liquid state, molecules have lower energy than in the gaseous state.
  • The process of condensation is exothermic, meaning energy is released to the surroundings during the phase change.
  • This decrease in internal energy does not affect the temperature of the water until the phase change is complete.

Additional Information

  • Internal Energy:
    • Internal energy is the sum of the kinetic and potential energies of the molecules in a system.
    • It depends on the state of matter (solid, liquid, gas) and temperature.
    • In gases, molecules have higher kinetic energy compared to liquids or solids.
  • Latent Heat:
    • Latent heat is the energy absorbed or released during a phase change without a change in temperature.
    • In condensation, latent heat is released as the system transitions from gas to liquid.
  • Phase Change:
    • A phase change is the transformation of matter from one state to another, such as from solid to liquid or liquid to gas.
    • Common phase changes include melting, freezing, vaporization, condensation, sublimation, and deposition.
  • Exothermic and Endothermic Processes:
    • Exothermic processes release energy to the surroundings (e.g., condensation, freezing).
    • Endothermic processes absorb energy from the surroundings (e.g., evaporation, melting).

Thermodynamics Question 2:

Zeroth law of thermodynamics is related to:

  1. internal energy
  2. temperature
  3. heat
  4. work

Answer (Detailed Solution Below)

Option 2 : temperature

Thermodynamics Question 2 Detailed Solution

CONCEPT:

Zeroth Law of Thermodynamics

  • The Zeroth Law of Thermodynamics deals with the concept of thermal equilibrium.
  • It states that if two systems are each in thermal equilibrium with a third system, then they are in thermal equilibrium with each other.
  • This law forms the basis for the definition of temperature.
  • It implies that temperature is the property that determines whether a system is in thermal equilibrium or not.

EXPLANATION

  • The Zeroth Law provides the foundation for the measurement of temperature.
  • It allows us to use a thermometer as the third system to measure the temperature of other systems.
  • Temperature: This is the correct answer, as the Zeroth Law establishes the concept of temperature as a measurable property.

Therefore, the correct answer is Temperature.

Thermodynamics Question 3:

ΔQ = ΔU + ΔW is equation for ___________

  1. Zeroth Law of Thermodynamics
  2. Third Law of Thermodynamics
  3. Second Law of Thermodynamics
  4. First Law of Thermodynamics

Answer (Detailed Solution Below)

Option 4 : First Law of Thermodynamics

Thermodynamics Question 3 Detailed Solution

The correct answer is First Law of Thermodynamics.

Key Points

  • The First Law of Thermodynamics is a version of the law of conservation of energy, adapted for thermodynamic processes.
  • It states that energy cannot be created or destroyed in an isolated system.
  • The change in the internal energy of a system (ΔU) is equal to the heat added to the system (ΔQ) minus the work done by the system on its surroundings (ΔW).
  • This can be mathematically expressed as ΔQ = ΔU + ΔW.

Additional Information

  • Internal Energy (U)
    • It is the total energy contained within a system, including kinetic and potential energy at the molecular level.
    • Changes in internal energy can result from heat transfer or work done.
  • Heat (Q)
    • It is a form of energy transfer between systems due to a temperature difference.
    • Heat transfer can occur through conduction, convection, or radiation.
  • Work (W)
    • In thermodynamics, work is the energy transferred when an object is moved by a force.
    • Positive work is done by the system when it expands against an external pressure.
  • Applications of the First Law
    • It is used to analyze various thermodynamic cycles such as the Carnot cycle, Otto cycle, and refrigeration cycles.
    • It helps in understanding the energy efficiency of engines and other systems.
  • Limitations
    • The First Law does not provide information about the direction of processes or the feasibility of reactions.
    • It does not explain entropy changes or the Second Law of Thermodynamics.

Thermodynamics Question 4:

Zeroth Law leads to the concept of ______

  1. Volume
  2. Temperature
  3. Pressure
  4. Work done 

Answer (Detailed Solution Below)

Option 2 : Temperature

Thermodynamics Question 4 Detailed Solution

The correct answer is Temperature.

Key Points

  • The Zeroth Law of Thermodynamics states that if two systems are each in thermal equilibrium with a third system, they are in thermal equilibrium with each other.
  • This law establishes the concept of temperature as a measurable and comparable quantity.
  • The Zeroth Law allows for the construction of thermometers to measure temperature based on the principle of thermal equilibrium.
  • Temperature is a scalar quantity that indicates the degree of hotness or coldness of a body or environment.
  • It is critical for defining the state of a system in thermodynamics and is key to understanding energy transfer processes like heat.

Additional Information

  • Thermal Equilibrium:
    • Two systems are in thermal equilibrium if there is no net flow of thermal energy between them.
    • It is a foundational concept in thermodynamics and a prerequisite for measuring temperature accurately.
  • Thermometers:
    • Devices used to measure temperature based on physical properties like expansion of mercury or electrical resistance.
    • They rely on the Zeroth Law to ensure consistent and accurate readings.
  • Temperature Scales:
    • Common scales include Celsius, Fahrenheit, and Kelvin.
    • Kelvin is the SI unit of temperature and starts from absolute zero, the lowest theoretically possible temperature.
  • Thermodynamics:
    • A branch of physics that deals with the relationships between heat, work, and energy.
    • The Zeroth Law complements the First, Second, and Third Laws of Thermodynamics in understanding energy systems.

Thermodynamics Question 5:

___ is zero for a cyclic process. 

  1. W
  2. ∆T
  3. Q
  4. ∆ U

Answer (Detailed Solution Below)

Option 4 : ∆ U

Thermodynamics Question 5 Detailed Solution

The correct answer is ∆U.

Key Points

  • In a cyclic process, the system returns to its initial state after completing the cycle, meaning the change in internal energy (∆U) is zero.
  • Internal energy (U) is a state function, and its value depends only on the state of the system, not on the path taken to reach that state.
  • The first law of thermodynamics states: ∆U = Q - W, where Q is heat added to the system, and W is work done by the system.
  • For a cyclic process, the initial and final states are the same, so the net internal energy change (∆U) is zero, regardless of the values of Q and W.
  • Examples of cyclic processes include Carnot cycles, Otto cycles, and Rankine cycles commonly used in thermodynamics and heat engines.

Additional Information

  • Cyclic Process
    • A thermodynamic process where the system undergoes changes but eventually returns to its initial state.
    • Examples include processes in heat engines, refrigeration cycles, and power plants.
  • Internal Energy (U)
    • The total energy contained within a system, including kinetic and potential energy at the molecular level.
    • It is a state function and depends only on the current state of the system (temperature, pressure, volume).
  • First Law of Thermodynamics
    • Expresses the principle of conservation of energy: energy cannot be created or destroyed; it can only change forms.
    • Mathematically: ∆U = Q - W, where Q is the heat added to the system, and W is the work done by the system.
  • Work (W) and Heat (Q)
    • Work is the energy transferred by a system to its surroundings due to macroscopic forces.
    • Heat is the energy transferred between systems due to a temperature difference.

Top Thermodynamics MCQ Objective Questions

ΔQ = ΔU + ΔW is equation for ___________

  1. Zeroth Law of Thermodynamics
  2. Third Law of Thermodynamics
  3. Second Law of Thermodynamics
  4. First Law of Thermodynamics

Answer (Detailed Solution Below)

Option 4 : First Law of Thermodynamics

Thermodynamics Question 6 Detailed Solution

Download Solution PDF

The correct answer is First Law of Thermodynamics.

Key Points

  • The First Law of Thermodynamics is a version of the law of conservation of energy, adapted for thermodynamic processes.
  • It states that energy cannot be created or destroyed in an isolated system.
  • The change in the internal energy of a system (ΔU) is equal to the heat added to the system (ΔQ) minus the work done by the system on its surroundings (ΔW).
  • This can be mathematically expressed as ΔQ = ΔU + ΔW.

Additional Information

  • Internal Energy (U)
    • It is the total energy contained within a system, including kinetic and potential energy at the molecular level.
    • Changes in internal energy can result from heat transfer or work done.
  • Heat (Q)
    • It is a form of energy transfer between systems due to a temperature difference.
    • Heat transfer can occur through conduction, convection, or radiation.
  • Work (W)
    • In thermodynamics, work is the energy transferred when an object is moved by a force.
    • Positive work is done by the system when it expands against an external pressure.
  • Applications of the First Law
    • It is used to analyze various thermodynamic cycles such as the Carnot cycle, Otto cycle, and refrigeration cycles.
    • It helps in understanding the energy efficiency of engines and other systems.
  • Limitations
    • The First Law does not provide information about the direction of processes or the feasibility of reactions.
    • It does not explain entropy changes or the Second Law of Thermodynamics.

When steam is converted into water, internal energy of the system

  1. Becomes zero
  2. Remains constant
  3. Increases
  4. Decreases

Answer (Detailed Solution Below)

Option 4 : Decreases

Thermodynamics Question 7 Detailed Solution

Download Solution PDF

The correct answer is Decreases.

Key Points

  • When steam condenses into water, it undergoes a phase change from gas to liquid, releasing latent heat in the process.
  • This release of latent heat leads to a decrease in the internal energy of the system.
  • The internal energy of a system is directly related to the kinetic and potential energy of its molecules; in the liquid state, molecules have lower energy than in the gaseous state.
  • The process of condensation is exothermic, meaning energy is released to the surroundings during the phase change.
  • This decrease in internal energy does not affect the temperature of the water until the phase change is complete.

Additional Information

  • Internal Energy:
    • Internal energy is the sum of the kinetic and potential energies of the molecules in a system.
    • It depends on the state of matter (solid, liquid, gas) and temperature.
    • In gases, molecules have higher kinetic energy compared to liquids or solids.
  • Latent Heat:
    • Latent heat is the energy absorbed or released during a phase change without a change in temperature.
    • In condensation, latent heat is released as the system transitions from gas to liquid.
  • Phase Change:
    • A phase change is the transformation of matter from one state to another, such as from solid to liquid or liquid to gas.
    • Common phase changes include melting, freezing, vaporization, condensation, sublimation, and deposition.
  • Exothermic and Endothermic Processes:
    • Exothermic processes release energy to the surroundings (e.g., condensation, freezing).
    • Endothermic processes absorb energy from the surroundings (e.g., evaporation, melting).

Zeroth Law leads to the concept of ______

  1. Volume
  2. Temperature
  3. Pressure
  4. Work done 

Answer (Detailed Solution Below)

Option 2 : Temperature

Thermodynamics Question 8 Detailed Solution

Download Solution PDF

The correct answer is Temperature.

Key Points

  • The Zeroth Law of Thermodynamics states that if two systems are each in thermal equilibrium with a third system, they are in thermal equilibrium with each other.
  • This law establishes the concept of temperature as a measurable and comparable quantity.
  • The Zeroth Law allows for the construction of thermometers to measure temperature based on the principle of thermal equilibrium.
  • Temperature is a scalar quantity that indicates the degree of hotness or coldness of a body or environment.
  • It is critical for defining the state of a system in thermodynamics and is key to understanding energy transfer processes like heat.

Additional Information

  • Thermal Equilibrium:
    • Two systems are in thermal equilibrium if there is no net flow of thermal energy between them.
    • It is a foundational concept in thermodynamics and a prerequisite for measuring temperature accurately.
  • Thermometers:
    • Devices used to measure temperature based on physical properties like expansion of mercury or electrical resistance.
    • They rely on the Zeroth Law to ensure consistent and accurate readings.
  • Temperature Scales:
    • Common scales include Celsius, Fahrenheit, and Kelvin.
    • Kelvin is the SI unit of temperature and starts from absolute zero, the lowest theoretically possible temperature.
  • Thermodynamics:
    • A branch of physics that deals with the relationships between heat, work, and energy.
    • The Zeroth Law complements the First, Second, and Third Laws of Thermodynamics in understanding energy systems.

___ is zero for a cyclic process. 

  1. W
  2. ∆T
  3. Q
  4. ∆ U

Answer (Detailed Solution Below)

Option 4 : ∆ U

Thermodynamics Question 9 Detailed Solution

Download Solution PDF

The correct answer is ∆U.

Key Points

  • In a cyclic process, the system returns to its initial state after completing the cycle, meaning the change in internal energy (∆U) is zero.
  • Internal energy (U) is a state function, and its value depends only on the state of the system, not on the path taken to reach that state.
  • The first law of thermodynamics states: ∆U = Q - W, where Q is heat added to the system, and W is work done by the system.
  • For a cyclic process, the initial and final states are the same, so the net internal energy change (∆U) is zero, regardless of the values of Q and W.
  • Examples of cyclic processes include Carnot cycles, Otto cycles, and Rankine cycles commonly used in thermodynamics and heat engines.

Additional Information

  • Cyclic Process
    • A thermodynamic process where the system undergoes changes but eventually returns to its initial state.
    • Examples include processes in heat engines, refrigeration cycles, and power plants.
  • Internal Energy (U)
    • The total energy contained within a system, including kinetic and potential energy at the molecular level.
    • It is a state function and depends only on the current state of the system (temperature, pressure, volume).
  • First Law of Thermodynamics
    • Expresses the principle of conservation of energy: energy cannot be created or destroyed; it can only change forms.
    • Mathematically: ∆U = Q - W, where Q is the heat added to the system, and W is the work done by the system.
  • Work (W) and Heat (Q)
    • Work is the energy transferred by a system to its surroundings due to macroscopic forces.
    • Heat is the energy transferred between systems due to a temperature difference.

Thermodynamics Question 10:

Zeroth law of thermodynamics is related to:

  1. internal energy
  2. temperature
  3. heat
  4. work

Answer (Detailed Solution Below)

Option 2 : temperature

Thermodynamics Question 10 Detailed Solution

CONCEPT:

Zeroth Law of Thermodynamics

  • The Zeroth Law of Thermodynamics deals with the concept of thermal equilibrium.
  • It states that if two systems are each in thermal equilibrium with a third system, then they are in thermal equilibrium with each other.
  • This law forms the basis for the definition of temperature.
  • It implies that temperature is the property that determines whether a system is in thermal equilibrium or not.

EXPLANATION

  • The Zeroth Law provides the foundation for the measurement of temperature.
  • It allows us to use a thermometer as the third system to measure the temperature of other systems.
  • Temperature: This is the correct answer, as the Zeroth Law establishes the concept of temperature as a measurable property.

Therefore, the correct answer is Temperature.

Thermodynamics Question 11:

ΔQ = ΔU + ΔW is equation for ___________

  1. Zeroth Law of Thermodynamics
  2. Third Law of Thermodynamics
  3. Second Law of Thermodynamics
  4. First Law of Thermodynamics

Answer (Detailed Solution Below)

Option 4 : First Law of Thermodynamics

Thermodynamics Question 11 Detailed Solution

The correct answer is First Law of Thermodynamics.

Key Points

  • The First Law of Thermodynamics is a version of the law of conservation of energy, adapted for thermodynamic processes.
  • It states that energy cannot be created or destroyed in an isolated system.
  • The change in the internal energy of a system (ΔU) is equal to the heat added to the system (ΔQ) minus the work done by the system on its surroundings (ΔW).
  • This can be mathematically expressed as ΔQ = ΔU + ΔW.

Additional Information

  • Internal Energy (U)
    • It is the total energy contained within a system, including kinetic and potential energy at the molecular level.
    • Changes in internal energy can result from heat transfer or work done.
  • Heat (Q)
    • It is a form of energy transfer between systems due to a temperature difference.
    • Heat transfer can occur through conduction, convection, or radiation.
  • Work (W)
    • In thermodynamics, work is the energy transferred when an object is moved by a force.
    • Positive work is done by the system when it expands against an external pressure.
  • Applications of the First Law
    • It is used to analyze various thermodynamic cycles such as the Carnot cycle, Otto cycle, and refrigeration cycles.
    • It helps in understanding the energy efficiency of engines and other systems.
  • Limitations
    • The First Law does not provide information about the direction of processes or the feasibility of reactions.
    • It does not explain entropy changes or the Second Law of Thermodynamics.

Thermodynamics Question 12:

When steam is converted into water, internal energy of the system

  1. Becomes zero
  2. Remains constant
  3. Increases
  4. Decreases

Answer (Detailed Solution Below)

Option 4 : Decreases

Thermodynamics Question 12 Detailed Solution

The correct answer is Decreases.

Key Points

  • When steam condenses into water, it undergoes a phase change from gas to liquid, releasing latent heat in the process.
  • This release of latent heat leads to a decrease in the internal energy of the system.
  • The internal energy of a system is directly related to the kinetic and potential energy of its molecules; in the liquid state, molecules have lower energy than in the gaseous state.
  • The process of condensation is exothermic, meaning energy is released to the surroundings during the phase change.
  • This decrease in internal energy does not affect the temperature of the water until the phase change is complete.

Additional Information

  • Internal Energy:
    • Internal energy is the sum of the kinetic and potential energies of the molecules in a system.
    • It depends on the state of matter (solid, liquid, gas) and temperature.
    • In gases, molecules have higher kinetic energy compared to liquids or solids.
  • Latent Heat:
    • Latent heat is the energy absorbed or released during a phase change without a change in temperature.
    • In condensation, latent heat is released as the system transitions from gas to liquid.
  • Phase Change:
    • A phase change is the transformation of matter from one state to another, such as from solid to liquid or liquid to gas.
    • Common phase changes include melting, freezing, vaporization, condensation, sublimation, and deposition.
  • Exothermic and Endothermic Processes:
    • Exothermic processes release energy to the surroundings (e.g., condensation, freezing).
    • Endothermic processes absorb energy from the surroundings (e.g., evaporation, melting).

Thermodynamics Question 13:

Zeroth Law leads to the concept of ______

  1. Volume
  2. Temperature
  3. Pressure
  4. Work done 

Answer (Detailed Solution Below)

Option 2 : Temperature

Thermodynamics Question 13 Detailed Solution

The correct answer is Temperature.

Key Points

  • The Zeroth Law of Thermodynamics states that if two systems are each in thermal equilibrium with a third system, they are in thermal equilibrium with each other.
  • This law establishes the concept of temperature as a measurable and comparable quantity.
  • The Zeroth Law allows for the construction of thermometers to measure temperature based on the principle of thermal equilibrium.
  • Temperature is a scalar quantity that indicates the degree of hotness or coldness of a body or environment.
  • It is critical for defining the state of a system in thermodynamics and is key to understanding energy transfer processes like heat.

Additional Information

  • Thermal Equilibrium:
    • Two systems are in thermal equilibrium if there is no net flow of thermal energy between them.
    • It is a foundational concept in thermodynamics and a prerequisite for measuring temperature accurately.
  • Thermometers:
    • Devices used to measure temperature based on physical properties like expansion of mercury or electrical resistance.
    • They rely on the Zeroth Law to ensure consistent and accurate readings.
  • Temperature Scales:
    • Common scales include Celsius, Fahrenheit, and Kelvin.
    • Kelvin is the SI unit of temperature and starts from absolute zero, the lowest theoretically possible temperature.
  • Thermodynamics:
    • A branch of physics that deals with the relationships between heat, work, and energy.
    • The Zeroth Law complements the First, Second, and Third Laws of Thermodynamics in understanding energy systems.

Thermodynamics Question 14:

___ is zero for a cyclic process. 

  1. W
  2. ∆T
  3. Q
  4. ∆ U

Answer (Detailed Solution Below)

Option 4 : ∆ U

Thermodynamics Question 14 Detailed Solution

The correct answer is ∆U.

Key Points

  • In a cyclic process, the system returns to its initial state after completing the cycle, meaning the change in internal energy (∆U) is zero.
  • Internal energy (U) is a state function, and its value depends only on the state of the system, not on the path taken to reach that state.
  • The first law of thermodynamics states: ∆U = Q - W, where Q is heat added to the system, and W is work done by the system.
  • For a cyclic process, the initial and final states are the same, so the net internal energy change (∆U) is zero, regardless of the values of Q and W.
  • Examples of cyclic processes include Carnot cycles, Otto cycles, and Rankine cycles commonly used in thermodynamics and heat engines.

Additional Information

  • Cyclic Process
    • A thermodynamic process where the system undergoes changes but eventually returns to its initial state.
    • Examples include processes in heat engines, refrigeration cycles, and power plants.
  • Internal Energy (U)
    • The total energy contained within a system, including kinetic and potential energy at the molecular level.
    • It is a state function and depends only on the current state of the system (temperature, pressure, volume).
  • First Law of Thermodynamics
    • Expresses the principle of conservation of energy: energy cannot be created or destroyed; it can only change forms.
    • Mathematically: ∆U = Q - W, where Q is the heat added to the system, and W is the work done by the system.
  • Work (W) and Heat (Q)
    • Work is the energy transferred by a system to its surroundings due to macroscopic forces.
    • Heat is the energy transferred between systems due to a temperature difference.
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